Institute of Leather Engineering and Technology

Notice

Event

Details of Dr. Md. Abdul Mottalib


Education: B. Sc (Hons), M. Sc (Chemistry), Ph. D (J.U.), DAAD Fellow, Germany.

                       Postdoc Fellow of Royal Society of Chemistry, England.

                       Postdoc Fellow of Swedish Science Research Council, Sweden.

 

Position: Associate Professor (since July 2001)

Experience: 23 years

Research Interest:

¨ Medicinal Chemistry- Synthesis and characterization of chiral and prochiral phosphine based Co, Rh, Ru complexes and to investigate their catalytic behavior in Asymmetric catalysis specially in respect of chiral drug synthesis.

¨ On cleaning technology, solid and liquid wastes management and use of wastage for value added production, assessment and reduction of pollutants in tanning industry.

 

e-mail: abdul.mottalib@du.ac.bd

List of publications:

 

1.         Investigation onto Soil Salinity of Hazaribagh Tanning Industrial Area, Dhaka, Bangladesh: M. A. Mottalib, A. Sultana, M. M. Rahman,  G. Zilani, S. Chowdhury and S.  Hoque; IOSR J. Env. Sci, Toxicol. and Food Tech., Accepted.

2.         Reduction of pollutants of tannery wastewater by using acidic waste liquor: M. A. Mottalib, M. M. Alam, A. Afrose and A. N. M. Al-Razee; IOSR J. Env. Sci, Toxicol. and Food Tech., 2017, 11(3), 28-33.

3.         Assessment of lead in water, sediments, soils and vegetables grown on the bank of Shitalakhya river, Bangladesh, A. N. M. Al-razee, M. N. Abser, M. A. Mottalib and M. Z. H. Ansary; J. Bangladesh Acad. Sci., 2016, 40(2), 91-99.

             4.         Heavy metal concentrations in contaminated soil and vegetables of tannery area in  Dhaka, Bangladesh: M. A. Mottalib, S. H.              Somoal, M. A. A. Shaikh and M. S. Islam;  Int. J. Curr. Res., 2016, 8(5), 30369-373.

5.         Assessment of Physico-Chemical Properties of Surface Water in Shitalakhya River, Polash, Narsingdi, Bangladesh : M. A. Mottalib,  A. N. M. Al-Razee,  M. N. Abser and E.U. M. Aman; Int. J. Adv. Res., 2016, 4(8), 915-924.

6.         Chiral diphosphine derivatives of alkylidyne tricobalt clusters-A comparative study of different cobalt carbonyl catalysts for (asymmetric) intermolecular Pauson-Khand reaction: M. A. Mottalib, M. Haukka and E. Nordlander ; Polyhedron, 2016, 103 (Part B), 275-282.

7.         Assessment of heavy metals in tannery waste-contaminated poultry feed and their accumulation in different edible parts of chicken: M. A. Mottalib,  A. Sultana,S. H. Somoal and  M. N. Abser; IOSR J. Env. Sci, Tox. and Food Tech., 2016, 10(11), 72-78. 

8.         Removal of chromium from tannery wastewater by tannery lime liquor; A very cost effective method : M. A. Mottalib, S. H. Somoal, M. S. Islam, M. N. Alam and M. N. Abser ; Int. J. Curr. Res., 2015, 7(6), 16795-98.

9.         A simple effective treatment of tannery effluents: M. A. Mottalib, T. K. Mim and M. N. Abser; J. Bang. Aca. Sci., 2014, 38(2), 235-239.

10.       Uptake and translocation of metals in different parts of crop plants irrigated with contaminated water from DEPZ area of Bangladesh : M. A. Goni, J. U. Ahmed, M. A. Halim, M. A. Mottalib and D. A. Chowdhury; Bull Environ Contam Toxicol, 2014, 92, 726-732.

11.       Carbon-phosphorus and carbon-hydrogen bond activation of tri(2-thienyl)phosphine at dirhenium and dimanganese centers : M. N. Uddin, M. A. Mottalib, N. Begum, S. Ghosh, A. K. Raha, D. T. Haworth, S. V. Lindeman, T. A. Siddiquee, D. W. Bennett, G. Hogarth, E. Nordlander and S. E. Kabir ; Organometallics, 2009, 28, 1514-1523 .

12.       Chiral and achiral phosphine derivatives of alkylidyne tricobalt carbonyl clusters as catalyst precursors for (asymmetric) inter- and intramolecular Pauson-Khand reactions: V. Moberg, M. A. Mottalib, D. Sauer, Y. Poplavskaya, D. C. Craig, S. B. Colbran, A. J. Deeming and E. Nordlander; Dalton Trans., 2008, 2442-2453.

13.       Two modes of C-H bond activation of tris(2-thienyl)phosphine in trinuclear osmium carbonyl clusters: M. A. Mottalib, S. E. Kabir, A. J. Deeming and E. Nordlander ; J. Organomet. Chem., 2007, 692, 5007-5017.

14.       Electrogeneration of Al-oxyhydroxide and its characterization: H. A. Shimul, M. Y. A. Mollah and M. A. Mottalib; J. Bang. Aca. Sci., 2007, 31(1), 143-149.

15.       Syntheses and Fluxional processes of Diphenyl(2- thienyl)phosphane Derivatives of Triosmium Clusters : N. K. K. Kazemifar, M. J. Stchedroff, M. A. Mottalib, Simona Selva, M. Monari, and E. Nordlander;  Eur.J. Inorg. Chem., 2006, 2058-2068.

16.       Reactions of [(µ-H)Os3(CO)10(µ-OMe)] and [(µ-H)Os3(CO)9(µ-OMe)(MeCN)] with dppm, dppe, dppp, and PPh2H: X-ray Crystal Structures of [(µ-H)Os3(CO)8(µ-OMe)(µ22-dppm)] and [(µ-H)Os3(CO)9(µ-OMe)(PPh2H)] : S. E. Kabir, M. A. Mottalib, G. M. G. Hossain, E. Nordlander and E. Rosenberg; Polyhedron , 2006, 25, 95-104.

17.       Reactions of Electron-Deficient Triosmium Clusters with diazomethane: Electrochemical Properties and Computational Studies of Charge Distribution: M. A. Mottalib, N. Begum, S. M. T Abedin, T. Akter, S. E. Kabir, M. A. Miah, D. Rokhsana, E. Rosenberg, G. M. Hossain and K. I. Hardcastle; Organometallics, 2005, 24(20), 4747-4759.

18.       Reaction [Os3(m-H)(m-OH)(CO)10] with PPh2H : X-ray crystal structure of [Os3(m-H)2(CO)8(m-PPh2)2]. : M. A. Mottalib, N. Begum, S. E. Kabir and G. M. G. Hossain; J. Bang. Aca. Sci., 2005, 29(2), 135-143.

19.       X-ray crystal structure of [(µ-H)2Os3(CO)8(m-dppm)] : S. E. Kabir, M. A. Mottalib and K. M. A. Malik; J. Bang. Aca. Sci., 2004, 28(1), 51-55.

20.       Combination of 1,2-hydroboration and 1,1-organoboration: synthesis of novel organo-substituted 1-silacyclobutenes : B. Wrackmeyer,  H. E. Maisel, E. Molla and M. A. Mottalib A. Badshah, M. H. Bhatti and S. Ali; Appl. Organomet. Chem., 2003, 17, 465-472.

21.       Synthesis and X-ray crystal structure of [(m-H)2(Cl)Os3(CO)9{m3-h2-C(C9H5)(4-CH3)N}] : M. I. Hyder, S. E. Kabir, M. A. Miah, M. A. Mottalib and K. M. A. Malik; J. Bang. Aca. Sci., 2003, 27(2), 175-185.

22.       Reaction of [Os3(CO)9{m3-h2-C7H3(2-CH3)NS}(m-H)] with diazomethane. The first example of a trimetallic cluster containing a m-methylidene and a methyl : S. E. Kabir, K. M. A. Malik, H. S. Mandal, M. A. Mottalib and E. Rosenberg ; Organometallics,  2002, 21, 2593-2595.

23.       Sulfido triosmium clusters containing bridging dppm ligand: crystal structures of   [Os3(CO)7(m3-CO) (m3-S) (m-dppm)] and two isomers of [Os3(CO)7(m3-S)2(m-dppm)] : K. A. Azam, S. E. Kabir, M. A. Mottalib, N. C. Sarker and K. M. A. Malik; Polyhedron, 2002, 21,381-387.

24.       Reactivity of the unsaturated triosmium cluster [(m-H)Os3(CO)8{Ph2PCH2P(Ph)C6H4}] with thiols : S. M. T Abedin, K. A. Azam, M. B. Hursthouse, S. E. Kabir, K. M. A. Malik, M. A. Mottalib and E. Rosenberg ; J. Cluster Sci., 2001, 12(1), 5-22.          

25.       Reactivity of the unsaturated triosmium cluster [(m-H)Os3(CO)8Ph2PCH2P(Ph)- C6H4}] with dithiols: X-ray structures of [Os3(CO)8(m-SCH2CH2CH2S)(Ph2PCH2PPh2)]. 1/2CH2Cl2 and [(m-H)Os3(CO)7(m3-h3-SCH2CH2CHS)(Ph2PCH2PPh2)] .1/2H2O : S. E. Kabir, C. A. Johns, K. M. A. Malik, M. A. Mottalib and E. Rosenberg ; J. Organomet. Chem., 2001, 625(1), 112-120.

26.       New zwitterionic heterocycyles derived from 1-chloro(dimethyl)silyl-1-borylalkenes and 2-lithio-1-methylimidazol and 1- lithio-indazole : B. Wrackmeyer, H. E. Maisel, W. Milius, A. Badshah, E. Molla and M. A. Mottalib ; J. Organomet. Chem., 2000, 602, 45-50.

27.       Reactivity of [(m-H)Os3(CO)8{Ph2PCH2P(Ph)C6H4}] with organic heterothiols: X-ray structures of [H(m-H)Os3(CO)8(h2-pyS){Ph2PCH2P(Ph)C6H4}] and [Os3(CO)8(m-h2-pyS){Ph2PCH2P(Ph)C6H4}] : S. E. Kabir, K. M. A. Malik, E. Molla and M. A. Mottalib ; J. Organomet. Chem., 2000, 616, 157-164.

28.       Dithiolate complexes of ruthenium and osmium: X-ray structures of [Ru2(CO)6(m-SCH2CH2S)] and [{(m-H)M3(CO)10}2(m-SCH2CH2CH2S)] (M=Ru, Os) : K. M. Hanif, S. E. Kabir, M. A. Mottalib, M. B. Hursthouse, K. M. A. Malik, and E. Rosenberg; Polyhedron, 2000, 19, 1073-1080.

29.       Metallation of 2-methyl-2-thiazoline at a triosmium cluster: X-ray structure of [(m-H)Os3(CO)10(m-h2-CH2C=NCH2CH2S)] : K. A. Azam, R. Dilshad, S. E. Kabir, M. A. Mottalib, M. B. Hursthouse and K. M. A. Malik; Polyhedron, 2000, 19, 1081-1084.

30.       Novel triosmium clusters derived from the reaction of [Os3(CO)10(m-Ph2PCH2PPh2)] with 1-vinylimidazole : J. Akter, K. A. Azam, S. E. Kabir, K. M. A. Malik and M. A. Mottalib ; Inorg. Chem. Commum., 2000, 3, 553-556.

31.       Carboxylation of a m3-diazo methylidyne triosmium cluster : S. M. T Abedin, K. I. Hardcastle, S. E. Kabir, K. M. A. Malik, M. A. Mottalib, E. Rosenberg and M. J. Abedin ; Organometallics, 2000, 19, 5623-5627.

32.       Aspects of triosmium clusters: S. E. Kabir and M. A. Mottalib; Chemical Review, Jahangirnagar University, Bangladesh, 2000, 25-45.

33.       Hydroboration of 1-alkynyl(chloro)silanes-new synthons in heterocyclic chemistry : B. Wrackmeyer, A. Badshah, E. Molla and M. A. Mottalib; J. Organomet. Chem., 1999, 584, 98-102.

34.       X-ray structure of [Os3(CO)10(m-Ph2PCH2PPh2)] : K. A. Azam, M. B. Hursthouse, S. E. Kabir, K. M. A. Malik and M. A. Mottalib; J. Chem. Crystallogra. 1999, 29, 813-818.       

 

35.       The coordination and reactivity of diphenyl-benzothienyl phosphine with [Os3(CO)12] and [H2Os3(CO)10] : the first sulfur-cluster coordination of a phosphobenzothiophene without ring opening: N. K. K. Kazemifar, M. J. Stchedroff, M. Monari, M. H. Johansson, M. A. Mottalib and E. Nordlander ; J. Chem. Soc. Dalton Trans. (submitted).    

36.       Synthesis and characterization of chiral diphosphine based clusters and their catalytic potentiality in asymmetric catalysis: M. A. Mottalib, S. Hauser, E. Schutz, A. Manna, M, Monari and E. Nordlander; (in preparation).

37.       Synthesis and characterization of chiral phosphine derivatives of cobalt-carbyne clusters and a comparative studies of their catalytic behavior with Co2(CO)8 and Co4(CO)12 in Pauson-Khand asymmetric reactions: M. A. Mottalib and E. Nordlander (in preparation).

38.       Ferrocene baesd chiral diphosphine derivatives of tri and tetra-ruthenium clusters as catalysts and catalysts precursors in hydrogenation of unsaturated organic acid and their enantiomeric access: M. A. Mottalib, S. Hauser, E. Schutz, A. Manna, M, Monari and E. Nordlander; (in preparation).

 

Oral presentation and Abstracts:

1.         Synthesis and characterization of chiral [(m-H)3Os3Rh(CO)10(diphosphine)] clusters and an investigation of their catalytic potentiality in the hydrogenation of unsaturated carboxylic acid : M. A. Mottalib and E. Nordlander ; 16th Asian Chemical Congress, 2016, Abstract, IC-OP-19.

2.         Chromium in tannery wastes water and it’s effect on local environment:  M. A. Mottalib, A. K. Deb, and M. F. Karim; Bang. Chem. Cong.; 2004, Abstract, A 11.

3.         Reactions of [(m-H)Os3(CO)9{m3-h2-C9H5(4-CH3)N}] and [(m-H)Os3(CO)9{m3-h2-C9H6- N}] with diazomethane : M. A. Mottalib, S. M. T Abedin, K. A. Azam, S. E. Kabir, and K. M. A. Malik ; Bang. Chem. Soc. Int. Conf., 2001, Abstract 16.

4.         Triosmium clusters containing bridging CNN, CCOOH, Dppm and Hydride  ligands : M. A. Mottalib, S. M. T. Abedin, S. E. Kabir, and K. M. A. Malik ; Bang. Chem.  Soc. Int. Conf.; 2001 Abstract, 17.

5.      Unusual metal-metal bonding in triosmium cluster: Synthesis, reactivity and  crystal structure of              [Os3(CO)9{m3-h2-C7H3(2-CH3)NS}(m-CH2)CH3] : M. A. Mottalib, S. E. Kabir, K. M. A. Malik,         H. S. Mandal and E. Rosenberg ; Bang. Chem.  Soc. Int. Conf.; 2001 Abstract, 19.

Poster presentation

 

  1. Impact of Fertilizer factories effluent on the surface water of Shitalakhya River, Narsingdi, Bangladesh: A. N. M. Al-razee, M. N. Abser and M. A. Mottalib; International Seminar on Fertilizer Factory Effluent, India, March 15-17, 2016.

 

  1.  Treatment of tannery effluent using no chemicals: P. Kumar, T. Haque, M. A. Mottalib and M. N. Abser; 16th Asian Chemical Congress, March 16-19, 2016, Dhaka, Bangladesh.